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Transition Metal-catalysed Carbonylation Reactions of Unsaturated Hydrocarbons

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Release : 2022
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Book Synopsis Transition Metal-catalysed Carbonylation Reactions of Unsaturated Hydrocarbons by : Ricarda Dühren

Download or read book Transition Metal-catalysed Carbonylation Reactions of Unsaturated Hydrocarbons written by Ricarda Dühren. This book was released on 2022. Available in PDF, EPUB and Kindle. Book excerpt:

Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes

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Release : 2001-11-30
Genre : Science
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Book Rating : 209/5 ( reviews)

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Book Synopsis Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes by : A.E. Shilov

Download or read book Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes written by A.E. Shilov. This book was released on 2001-11-30. Available in PDF, EPUB and Kindle. Book excerpt: hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the “noble gases of organic chemistry” and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint.

Reactions of Unsaturated Hydrocarbons Catalysed by Transition Metal Compounds

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Release : 1998
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Book Synopsis Reactions of Unsaturated Hydrocarbons Catalysed by Transition Metal Compounds by :

Download or read book Reactions of Unsaturated Hydrocarbons Catalysed by Transition Metal Compounds written by . This book was released on 1998. Available in PDF, EPUB and Kindle. Book excerpt:

Homogeneous Transition-metal Catalysis

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Release : 2012-12-06
Genre : Science
Kind : eBook
Book Rating : 803/5 ( reviews)

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Book Synopsis Homogeneous Transition-metal Catalysis by : Christopher Masters

Download or read book Homogeneous Transition-metal Catalysis written by Christopher Masters. This book was released on 2012-12-06. Available in PDF, EPUB and Kindle. Book excerpt: Soluble catalysts are used extensively in many branches of chemistry and are indeed a vital constituent of many natural processes. They find wide application throughout the chemical industry where they assist in the production of several million tonnes of chemicals each year. Since homogeneous systems, especially those incorporating transition metals, often function effectively under milder conditions than their heterogeneous counterparts, they are becoming increasingly important at a time when the chemical industry in particular, and society in general, is seeking ways of conserving energy and of making the best possible use of available resources. My principal objective in- writing this book is to engender sufficient enthusiasm for, and knowledge of, the subject in the reader that he or she will be encouraged to begin, or continue, to make their own contribution to advancing our knowledge of homogeneous catalysis. After attempting to acquaint the reader with some of the ground rules I have tried to describe the present scope, and the future potential, of this fascinating field of chemistry by drawing both on academic and on industrial data sources. This approach stems from a personal conviction that future progress could be considerably hastened by a more meaningful dialogue between chemists working both in industrial and in academic research institutions. Wherever possible, examples of the commercial application of homogeneous catalyst systems have been included and no attempt has been made in any way to disguise the many unresolved questions and exciting challenges which still pervade this rapidly developing area.

Addition Reactions with Unsaturated Hydrocarbons

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Release : 2022-02-28
Genre : Science
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Book Rating : 82X/5 ( reviews)

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Book Synopsis Addition Reactions with Unsaturated Hydrocarbons by : Ruimao Hua

Download or read book Addition Reactions with Unsaturated Hydrocarbons written by Ruimao Hua. This book was released on 2022-02-28. Available in PDF, EPUB and Kindle. Book excerpt: Addition Reactions with Unsaturated Hydrocarbons Provides comprehensive coverage of the atom-economic approach to functionalized molecules using unsaturated hydrocarbons as starting materials Unsaturated hydrocarbons have emerged as an important class of fundamental starting materials in organic synthesis. Synthetic methodologies incorporating unsaturated hydrocarbons continue to expand due to their numerous applications in the synthesis of a vast array of chemicals. Addition Reactions with Unsaturated Hydrocarbons presents an up-to-date overview of modern methods that utilize reactions of unsaturated hydrocarbons as building blocks of organic synthesis, covering the conceptual and practical knowledge required for designing atom-efficient reactions to synthesize functionalized molecules. This authoritative volume discusses homo-dimerization and cross-dimerization of alkynes and/or alkenes, synthesis of carbonyl compounds from the hydration of alkynes, cycloadditions of alkynes and alkenes for the synthesis of carbocycles and heterocycles, double functionalization of alkynes and alkenes by addition reactions of element-element bonds, and more. Summarizes the most recent developments in the reactions of unsaturated hydrocarbons Features more than 600 schemes describing typical reactions starting from unsaturated hydrocarbons Covers topics such as alkynylated reactions, addition and cycloaddition reactions of alkynes and alkenes, and carbonylation of alkynes and alkenes with carbon monoxide Includes examples of synthesis procedures of natural products involving alkyne transformation With comprehensive coverage of important reactions of unsaturated hydrocarbons, Addition Reactions with Unsaturated Hydrocarbons is a valuable resource for organic chemists, pharmaceutical chemists, and biochemists in both academia and industry as well as an excellent reference text for graduate students in relevant areas of chemistry.

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