Author : Adam Blickley
Release : 2018
Genre : Energy storage
Kind : eBook
Book Rating : /5 ( reviews)
Book Synopsis Synthesis and Electrochemical Characterization of Layered Oxides for Aqueous Energy Storage by : Adam Blickley
Download or read book Synthesis and Electrochemical Characterization of Layered Oxides for Aqueous Energy Storage written by Adam Blickley. This book was released on 2018. Available in PDF, EPUB and Kindle. Book excerpt: Energy storage devices are quickly becoming a major requirement for human society, especially with the advancement of renewable energy and the rise of electric cars. However, current energy storage technologies can be dangerous, environmentally unfriendly, and expensive. Li-ion batteries, the most common rechargeable energy storage devices used commercially, utilize flammable electrolytes and in some cases toxic electrode materials. In order to overcome these drawbacks, new rechargeable energy storage devices are being investigated. One such technology that can address many of these issues is an aqueous-based energy storage device. These energy storage systems use water as the electrolyte solvent rather than expensive, environmentally hazardous, and flammable organic compounds. Aqueous energy storage devices tend to exhibit pseudocapacitance, and because of this, are often called "pseudocapacitors." Pseudocapacitance is a form of energy storage behavior that may exhibit both surface or near-surface reactions as well as some form of intercalation mechanism. Unlike typical battery intercalation reactions, pseudocapacitive storage is not limited by the diffusion of intercalating species. The focus of this thesis research is on the effect of structure and composition of layered transition metal oxide electrodes on their intercalation-based pseudocapacitive properties in aqueous systems Chemically preintercalated vanadium oxide (Îþ-MxV2O5, M = Li, Na, K, Mg, and Ca), which has been previously studied in non-aqueous Li-, Na-, and K-ion batteries, was investigated for its aqueous pseudocapacitive capabilities. First, the effect of post synthesis treatments on the initial capacitance and capacitance retention of Îþ-NaxV2O5 samples was investigated in order to identify the treatment combination leading to the highest performance. It was found that Îþ-NaxV2O5 samples that were aged and hydrothermally treated demonstrated the highest initial capacitance values of 230 F/g while samples that were aged and vacuum annealed exhibited the best capacitance retentions (68% after 50 cycles). The aged and hydrothermally treated and the aged and annealed post-synthesis treatment combinations were used on all five preintercalated Îþ-MxV2O5, materials (M = Li, Na, K, Mg, and Ca) and the effect of preintercalated ion on pseudocapacitive performance was studied. For all five phases, and a pH study was conducted to investigate the relationship between electrolyte pH and vanadium oxide stability in aqueous electrolyte. It was found that by lowering the pH from 6.67 to 2.35, an increase in capacitance retention of up to 35% and an increase in initial capacitance of 39 F/g could be achieved. The best initial capacity of 214 F/g observed was for aged and annealed Îþ-CaxV2O5 at a pH of 2.35. The highest capacity retention observed was 96.1 % for aged and hydrothermally treated of Îþ-LixV2O5 ℗Ơat a pH of 2.35. The second part of this master's research was focused on the adaptation of the chemical preintercalation method developed in the Materials Science and Engineering group at Drexel for the fabrication of new layered transition metal oxides beyond vanadium oxide. For the first time, a novel family of layered tungsten oxides (MxWO3℗ʺnH2O, M= Na, K, Mg, and Ca) was synthesized. Na0.2WO3℗ʺ0.8H2O phase demonstrated an initial capacitance of 60 F/g in an aqueous-based 1M H2SO4 electrolyte. Also, a pressure induced color change phenomenon was observed.
