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Synthesis and Application of Organoboron Compounds

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Release : 2015-03-04
Genre : Science
Kind : eBook
Book Rating : 544/5 ( reviews)

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Book Synopsis Synthesis and Application of Organoboron Compounds by : Elena Fernández

Download or read book Synthesis and Application of Organoboron Compounds written by Elena Fernández. This book was released on 2015-03-04. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis

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Release : 2020-05-22
Genre : Science
Kind : eBook
Book Rating : 732/5 ( reviews)

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Book Synopsis Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis by : E. Fernández

Download or read book Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis written by E. Fernández. This book was released on 2020-05-22. Available in PDF, EPUB and Kindle. Book excerpt: The widespread use of organoboron compounds justifies the efforts devoted to their synthesis, as well as toward developing an understanding of their reactivity. The nature of the mono- or diboron species is of paramount importance in determining the reversible covalent binding properties of the boron atom with both nucleophiles and electrophiles. By wedding the rich chemical potential of organoboron compounds to the ubiquity of organic scaffolds, advanced borylation reactions have the potential to open unprecedented synthetic alternatives, and new knowledge in the field should encourage chemists to use organoboron compounds. In this volume, the main objective is to provide a collection of the most useful, practical, and reliable methods, reported mainly within the last decade, for boron activation and boron reactivity. The volume covers the main concepts of organoboron compounds and includes experimental procedures, enabling newcomers to the field the instant and reliable application of the new tools in synthesis. Rather than aiming for a comprehensive coverage, the most advanced solutions for challenging transformations are introduced. To this end, a team of pioneers and leaders in the field have been assembled who discuss both the practical and conceptual aspects of this rapidly growing field.

Organoborane Chemistry

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Release : 2012-12-02
Genre : Science
Kind : eBook
Book Rating : 615/5 ( reviews)

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Book Synopsis Organoborane Chemistry by : Thomas Onak

Download or read book Organoborane Chemistry written by Thomas Onak. This book was released on 2012-12-02. Available in PDF, EPUB and Kindle. Book excerpt: Organoborane Chemistry deals with the chemistry of organoboranes, with emphasis on compounds containing a carbon-boron bond. The structure and physical properties of organoboranes are discussed, along with the reactions of three-coordinate and four-coordinate organoboranes, organodiboranes, and other organopolyboranes such as organotetraboranes and organopentaborane compounds. Comprised of seven chapters, this book begins with an overview of multistep synthetic or degradative reactions involving organoboron compounds, along with the nomenclature for such compounds. The next chapter examines the structure and physical properties of organoboranes, with emphasis on boron-carbon bond lengths, electronic transitions, and molecular orbital calculations. Subsequent chapters focus on three-coordinate and four-coordinate organoboranes, together with their synthesis, reactions, and properties; hydroboration and dehydroboration of organodiboranes; and the synthesis, reactions, and physical properties of other organopolyboranes such as organotetraboranes, organopentaborane compounds, and organodecaborane compounds. The final chapter is devoted to cyclic boron-carbon systems and the applications of organoboron compounds. This monograph should be of interest to organic chemists.

Synthesis of Functionalized Organoboron Compounds Through Copper(I) Catalysis

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Release : 2017-06-27
Genre : Science
Kind : eBook
Book Rating : 351/5 ( reviews)

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Book Synopsis Synthesis of Functionalized Organoboron Compounds Through Copper(I) Catalysis by : Koji Kubota

Download or read book Synthesis of Functionalized Organoboron Compounds Through Copper(I) Catalysis written by Koji Kubota. This book was released on 2017-06-27. Available in PDF, EPUB and Kindle. Book excerpt: This book describes state-of-the-art borylation chemistry using copper(I) catalysis. Enantioselective reactions are included to afford a variety of functionalized, complex organoboronate esters, which will find wide application in asymmetric synthesis, drug discovery, and material science. Organoboron compounds are recognized as useful reagents in organic synthesis; therefore, great effort has been devoted to the development of a simple, mild, and efficient method for their preparation in the past several years. However, the synthesis of functionalized organoboron compounds remains a challenging issue because known reactions often require the use of highly reactive organometallic carbon nucleophiles. This book focuses on conceptually new, formal nucleophilic copper(I)-catalyzed borylation reactions with diboron compounds that show high selectivity and excellent functional group compatibility. Theoretical studies based on density functional theory calculations to understand the reaction mechanisms have also been described. Advances in this novel borylation chemistry will allow the rapid and efficient synthesis of complex molecules with potentially interesting properties in combination with the boron functionalization process.

Synthesis and Application of Organoboron Compounds for Catalytic Amide Formation and Bifunctional Catalysis

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Release : 2020
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Book Synopsis Synthesis and Application of Organoboron Compounds for Catalytic Amide Formation and Bifunctional Catalysis by : Yihao Du

Download or read book Synthesis and Application of Organoboron Compounds for Catalytic Amide Formation and Bifunctional Catalysis written by Yihao Du. This book was released on 2020. Available in PDF, EPUB and Kindle. Book excerpt:

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