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Surface Modification of Cyclic Olefin Polymers Using Atmospheric Pressure Jet

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Release : 2022
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Kind : eBook
Book Rating : /5 ( reviews)

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Book Synopsis Surface Modification of Cyclic Olefin Polymers Using Atmospheric Pressure Jet by : Faraj Abubaker Elammari

Download or read book Surface Modification of Cyclic Olefin Polymers Using Atmospheric Pressure Jet written by Faraj Abubaker Elammari. This book was released on 2022. Available in PDF, EPUB and Kindle. Book excerpt: The design and development of the plasma pressure jet is used throughout the thesis. The plasma jet's key components are discussed. Helium, argon, nitrogen, and air plasma were used to study the surface activation and bonding of cyclic olefin polymers. The plasma gas had a temperature less than 50 °C, making it suitable for polymer processing. The substrates were treated between 3 to 20 mm from the plasma exit. Air, as the plasma jet's feeding gas, creates a surface wettability of less than 10°. Water contact angle (WCA), scanning electron microscopy (SEM), atomic force microscopy (AFM), and infrared spectroscopy (IR) were used to characterise the substrate surface properties. This study establishes atmospheric pressure plasma as a cost-effective method for making cyclic olefin polymers hydrophobic and super hyderophilic. Secondly, design expert V12 software was used to optimize the APPJ operating parameters to obtain the lowest COP water contact angle with the lowest pricing. More research is required to optimise the polymer's surface and reduce the number of repetitive experiments. Therefore, the plasma jet was detailed to better facilitate understanding. Voltage and current probes were used for electrical measurements, and optical characterisation was performed using optical emission spectroscopy. Hydrophobic recovery of polymers is a concern in a variety of applications, most notably microfluidic devices. The work presented in Chapter 5 resulted in a stable surface that remained stable for more than 60 days and was partially stable for approximately 180 days. Finally, we modified the surface of disposable glass for biosensor applications. In order to improve the optical properties, the gold of different thickness can be tailored in this work by varying plasma jet parameters. The surface treated was characterised using UV-VIS spectroscopy and scanning electron microscopy. Although the results were not suitable for biosensor applications, the experiment was worthwhile.

Polymer Surface Modification Using Novel Underwater Plasma (UWP) Technique

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Release : 2010
Genre :
Kind : eBook
Book Rating : 024/5 ( reviews)

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Book Synopsis Polymer Surface Modification Using Novel Underwater Plasma (UWP) Technique by : Ranjit Sharad Joshi

Download or read book Polymer Surface Modification Using Novel Underwater Plasma (UWP) Technique written by Ranjit Sharad Joshi. This book was released on 2010. Available in PDF, EPUB and Kindle. Book excerpt:

Encyclopedia of Plasma Technology - Two Volume Set

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Release : 2016-12-12
Genre : Technology & Engineering
Kind : eBook
Book Rating : 318/5 ( reviews)

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Book Synopsis Encyclopedia of Plasma Technology - Two Volume Set by : J. Leon Shohet

Download or read book Encyclopedia of Plasma Technology - Two Volume Set written by J. Leon Shohet. This book was released on 2016-12-12. Available in PDF, EPUB and Kindle. Book excerpt: Technical plasmas have a wide range of industrial applications. The Encyclopedia of Plasma Technology covers all aspects of plasma technology from the fundamentals to a range of applications across a large number of industries and disciplines. Topics covered include nanotechnology, solar cell technology, biomedical and clinical applications, electronic materials, sustainability, and clean technologies. The book bridges materials science, industrial chemistry, physics, and engineering, making it a must have for researchers in industry and academia, as well as those working on application-oriented plasma technologies. Also Available Online This Taylor & Francis encyclopedia is also available through online subscription, offering a variety of extra benefits for researchers, students, and librarians, including: Citation tracking and alerts Active reference linking Saved searches and marked lists HTML and PDF format options Contact Taylor and Francis for more information or to inquire about subscription options and print/online combination packages. US: (Tel) 1.888.318.2367; (E-mail) [email protected] International: (Tel) +44 (0) 20 7017 6062; (E-mail) [email protected]

Surface Modification of Polymers Using OH Radicals and Energetic Neutrals [microform]

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Release : 1996
Genre : Ion bombardment
Kind : eBook
Book Rating : 209/5 ( reviews)

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Book Synopsis Surface Modification of Polymers Using OH Radicals and Energetic Neutrals [microform] by : June Q. Sun

Download or read book Surface Modification of Polymers Using OH Radicals and Energetic Neutrals [microform] written by June Q. Sun. This book was released on 1996. Available in PDF, EPUB and Kindle. Book excerpt: A special vacuum process has been developed for adding functional groups onto polymer surfaces with different reactivities. In this novel technique, polymer surfaces were exposed, in a vacuum chamber, to OH radicals generated by the dissociation of water vapour on hot rhenium wires. Laser-induced fluorescence spectroscopy was used to confirm the existence of the OH radicals in the reactor. It was found by X-ray photoelectron spectroscopy and high resolution electron energy loss spectroscopy that about half a monolayer equivalent of the C-OH group could be generated on a relatively reactive polymer like polystyrene with a 20 seconds exposure at a water pressure of $1\times 10\sp{-3}$ Torr. Further exposure of the polymer leads to the formation of other functional groups like the C-O-C, C=O and COOH on the surface. For surface engineering of more stable polymers, energetic neutrals were used to activate the polymer surfaces. In this process, the hot rhenium wires were used as thermionic emitter for gas phase electron impact ionization. The ions were subsequently accelerated with an electric field, and were then used to generate energetic neutrals by ion-molecule collisions. The energetic neutrals for activating an electrically insulating surface were controlled by the ion formation, ion acceleration, gas pressure (the mean-free path), and the separation between the ionization zone and the sample surface. With a filament temperature of 1600$\sp\circ$C, an accelerating voltage of 50 eV, a water pressure of $1\times 10\sp{-3}$ Torr (collision mean free path being about 5 cm), and an ion drifting distance of 12 cm, about 0.15 monolayer equivalent of the COH were added to teflon and 0.35 to polyethylene in 30 seconds.

Plasma Modification of Polyolefins

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Release : 2021-11-23
Genre : Technology & Engineering
Kind : eBook
Book Rating : 636/5 ( reviews)

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Book Synopsis Plasma Modification of Polyolefins by : N. S. Baneesh

Download or read book Plasma Modification of Polyolefins written by N. S. Baneesh. This book was released on 2021-11-23. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses plasma modification of polyolefin surfaces. It comprises 21 chapters divided into three major sections. The first section covers the different techniques used for plasma modification of polyolefin surfaces and the effects of various gases as a surrounding medium, while the second provides a detailed analysis of the physics and chemistry of plasma modification and discusses various innovative characterization techniques, as well as ageing of the modified surface. It focuses on the analysis of changes in polymers’ surface chemistry using various spectroscopic techniques, and of changes in their surface morphology after plasma treatment using optical microscopy, electron microscopy and atomic force microscopy. In addition, it provides detailed information on the characterization of modified polymer surfaces. The book’s third and last section covers a range of applications of plasma-modified polyolefin surfaces varying from the packaging industry to the biomedical field, and shares valuable insights on the lifecycle analysis of plasma modification and modified surfaces.

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