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Chemistry of Non-stoichiometric Compounds

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Release : 1994-01-13
Genre : Science
Kind : eBook
Book Rating : 139/5 ( reviews)

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Book Synopsis Chemistry of Non-stoichiometric Compounds by : Koji Kosuge

Download or read book Chemistry of Non-stoichiometric Compounds written by Koji Kosuge. This book was released on 1994-01-13. Available in PDF, EPUB and Kindle. Book excerpt: This unified presentation of the chemistry of non-stoichiometric compounds is the first monograph on the subject for two decades. Based on statistical thermodynamics and structural inorganic chemistry, with descriptions of modern examples and applications, this will be useful to both researchers in industry and undergraduates in solid state chemistry and physics.

Non-Stoichiometric Compounds

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Release : 2012-12-06
Genre : Science
Kind : eBook
Book Rating : 438/5 ( reviews)

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Book Synopsis Non-Stoichiometric Compounds by : J. Nowotny

Download or read book Non-Stoichiometric Compounds written by J. Nowotny. This book was released on 2012-12-06. Available in PDF, EPUB and Kindle. Book excerpt: The material in this book is based on invited and contributed pa pers presented at the NATO Advanced Research Workshop on INon-stoichio l metric Compounds held in Ringberg Castle, Rottach-Egern (Bavarian Alps), Germany, July 3-9, 1988. The workshop followed previous meetings held in Mogilany, Poland (1980), Alenya, France (1982), Penn State, USA (1984) and Keele University, UK (1986). The aim of these workshops is to present and discuss up-to-date knowledge in the study of non-stoichiometry and its effect on materials properties as well as to indicate the most urgent research pathways required in this field. Since the subject of non-stoichiometry is interdisciplinary, the workshops bring together solid state physicists and chemists, surface scientists, materials scientists, ceramists and metallurgists. The present workshop, which gathered 42 scientists of an inter national reputation, mainly considered the effect of surfaces, grain boundaries and structural defects on materials properties. From discus sions during this meeting it emerged that correct understanding of properties of ceramic materials requires urgent studies on the defect structure of the interface region. Progress in this direction requires the development of the interface defect chemistry. This is the task for materials scientists in the near future. The present proceedings includes both theoretical and experimen tal work on general aspects of non-stoichiometry, defect structure and diffusion in relation to the bulk and to the interface region of such materials as high tech ceramics, solid electrolytes, electronic cera mics, nuclear materials and high Tc oxide superconductors.

Non-Stoichiometric Compounds

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Release : 2013-10-22
Genre : Science
Kind : eBook
Book Rating : 76X/5 ( reviews)

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Book Synopsis Non-Stoichiometric Compounds by : D. J. M. Bevan

Download or read book Non-Stoichiometric Compounds written by D. J. M. Bevan. This book was released on 2013-10-22. Available in PDF, EPUB and Kindle. Book excerpt: Non-Stoichiometric Compounds: Tungsten Bronzes, Vanadium Bronzes and Related Compounds deals with the chemistry of non-stoichiometric compounds such as tungsten bronzes and vanadium bronzes. Topics covered include the thermodynamic basis for lattice defects and non-stoichiometry; thermodynamics of binary crystals; non-stoichiometry in ionic crystals; and interaction of defects. A structural view of non-stoichiometric compounds is also presented. Comprised of two parts, this volume begins with a historical account of developments in non-stoichiometry, focusing on the thermodynamic treatments and structural descriptions of non-stoichiometric compounds. The discussion then turns to the thermodynamic basis for lattice defects and non-stoichiometry, along with the thermodynamics of binary crystals and electronic defects in ionic crystals. Classical defect models are also described, and defect interactions in non-stoichiometric compounds are considered, together with the thermodynamics and crystallography in such compounds. The last section is devoted to tungsten bronzes, vanadium bronzes, and related compounds including bronzes of molybdenum, rhenium, niobium, tantalum, titanium, manganese, platinum, and palladium. This book is intended for inorganic chemists.

Nonstoichiometric Oxides

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Release : 2012-12-02
Genre : Science
Kind : eBook
Book Rating : 804/5 ( reviews)

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Book Synopsis Nonstoichiometric Oxides by : O.T. Soerensen

Download or read book Nonstoichiometric Oxides written by O.T. Soerensen. This book was released on 2012-12-02. Available in PDF, EPUB and Kindle. Book excerpt: Nonstoichiometric Oxides discusses the thermodynamic and structural studies of nonstoichiometric oxides. This eight-chapter text also covers the defect-defect interactions in these compounds. The introductory chapters describe the thermodynamic properties of nonstoichiometric oxides in terms of defect complexes using the classical thermodynamic principles and from a statistical thermodynamics point of view. These chapters also include statistical thermodynamic models that indicate the ordered nonstoichiometric phase range in these oxides. The subsequent chapters examine the transport properties, such as diffusion and electrical conductivity. Diffusion theories and experimental diffusion coefficients for several systems, as well as the electrical properties of the highly defective ionic and mixed oxide conductor, are specifically tackled in these chapters. The concluding chapters present the pertinent results obtained in nonstoichiometric oxide structural studies using high-resolution electron microscopy and X-ray and neutron diffraction. Inorganic chemists and inorganic chemistry teachers and students will greatly appreciate this book.

Disorder and Order in Strongly Nonstoichiometric Compounds

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Release : 2013-03-09
Genre : Technology & Engineering
Kind : eBook
Book Rating : 826/5 ( reviews)

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Book Synopsis Disorder and Order in Strongly Nonstoichiometric Compounds by : A.I. Gusev

Download or read book Disorder and Order in Strongly Nonstoichiometric Compounds written by A.I. Gusev. This book was released on 2013-03-09. Available in PDF, EPUB and Kindle. Book excerpt: Deals with the influence of stoiciometry and order/disorder on materials properties. It summarizes the knowledge available in a comprehensive way.

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