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Catalytic Asymmetric Reactions of Conjugated Nitroalkenes

2020-08-13 Science
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Release : 2020-08-13
Genre : Science
Kind : eBook
Book Rating : 23X/5 ( reviews)

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Book Synopsis Catalytic Asymmetric Reactions of Conjugated Nitroalkenes by : Irishi N.N. Namboothiri

Download or read book Catalytic Asymmetric Reactions of Conjugated Nitroalkenes written by Irishi N.N. Namboothiri. This book was released on 2020-08-13. Available in PDF, EPUB and Kindle. Book excerpt: Nitroalkenes have often been referred to as "synthetic chameleons" owing to their reactivity, synthetic utility and biological significance. In the last two decades, the reactivity of nitroalkenes as substrates in diverse catalytic asymmetric transformations has been of tremendous interest on account of the powerful abilities of the nitro group to coordinate and withdraw electrons, as well as its amenability to undergo a wide variety of synthetic transformations. Although numerous original articles and reviews have appeared in the literature, a monograph providing a comprehensive coverage of this topic was conspicuous by its absence. This book features: A systematic, up-to-date, in-depth and well-organized compilation, spread over 12 chapters, of various catalytic asymmetric reactions of nitroalkenes with diverse substrates reported to date A wide coverage of reactions such as Michael additions, Friedel–Crafts reactions, cycloadditions, asymmetric reductions, multicomponent and cascade reactions, as well as other miscellaneous reactions Various chiral organo, metal and even biocatalysts involved in the stereoselective synthesis of multifunctional adducts via catalytic asymmetric reactions of nitroalkenes Schemes and figures detailing all the reagents, reaction conditions and product profiles Mechanistic details, including transition state models, which will be useful for effective catalytic design This book will be an invaluable resource for those who are working in the area of asymmetric catalysis and synthetic methodologies.

Nitroalkenes

1994-08-16 Science
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Release : 1994-08-16
Genre : Science
Kind : eBook
Book Rating : /5 ( reviews)

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Book Synopsis Nitroalkenes by : V. V. Perekalin

Download or read book Nitroalkenes written by V. V. Perekalin. This book was released on 1994-08-16. Available in PDF, EPUB and Kindle. Book excerpt: Nitroalkenes reveals the great significance to theoretical and synthetic chemistry of this class of compounds. Over recent years the applications of nitroalkenes have expanded rapidly from established areas, such as rocket propulsion and explosives, into biotechnology, perhaps the science of the 1990s. The high reactivity of nitroalkenes makes them particularly suitable for the synthesis of biologically active compounds such as alkaloids, antibiotics, prostaglandins and biocides, etc. Nitroalkenes is a unique and up-to-date analysis written for all chemists working in organic synthesis and chemical technology. The fascinating versatility of these compounds makes this book particularly relevant to researchers in the pharmaceutical, aerospace and explosives industries.

The Nitro Group in Organic Synthesis

2003-05-08 Science
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Release : 2003-05-08
Genre : Science
Kind : eBook
Book Rating : 465/5 ( reviews)

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Book Synopsis The Nitro Group in Organic Synthesis by : Noboru Ono

Download or read book The Nitro Group in Organic Synthesis written by Noboru Ono. This book was released on 2003-05-08. Available in PDF, EPUB and Kindle. Book excerpt: The most useful reactions of organonitro compounds in organic synthesis Compounds containing nitro groups are useful intermediates for the synthesis of natural products and other complex organic molecules. The Nitro Group in Organic Synthesis focuses on reactions that proceed under mild conditions, important functional groups that can be synthesized by conversion of nitro groups, and the stereoselectivity of reactions of nitro compounds. These issues are of great importance to practicing researchers in today's pharmaceutical, agrochemical, and fine chemical industries. The Nitro Group in Organic Synthesis also emphasizes environmentally-friendly methods for nitration, the importance of aliphatic nitro compounds, and modern preparation of nitro compounds. Other topics discussed include: * Henry reaction * Asymmetric Michael addition * Alkylation, acylation, halogenation, and related reactions of RNO2 * Substitution and elimination of NO2 and RNO2 The Nitro Group in Organic Synthesis is a useful resource for researchers and students in organic and medicinal chemistry.

Nitroalkanes

2021-01-07 Science
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Release : 2021-01-07
Genre : Science
Kind : eBook
Book Rating : 769/5 ( reviews)

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Book Synopsis Nitroalkanes by : Roberto Ballini

Download or read book Nitroalkanes written by Roberto Ballini. This book was released on 2021-01-07. Available in PDF, EPUB and Kindle. Book excerpt: Discover a comprehensive exploration of recent progress in the preparation of nitroalkanes from two leading voices in the field Nitroalkanes: Synthesis, Reactivity, and Applications delivers a thorough summary of the importance of nitroalkanes in organic synthesis. The book covers their preparation, transformation into other functional groups, like carbonyls and amines, and their use in the formation of single carbon-carbon or double carbon-carbon bonds. The distinguished authors have included chapters on acyclic and cyclic alpha-nitro ketones as well as the synthesis of cyclopropanes and spiro ketals. The book provides treatments of the application of nitroalkanes for the synthesis of important heterocycles, poly-functionalized structures, natural products, and compounds of biological and pharmaceutical interest. A one-stop resource in a topic that hasn???t been fully addressed by any other book in decades, this book covers the most important synthetic routes toward nitroalkanes. Readers will also benefit from the inclusion of: A thorough introduction to the synthesis of nitroalkanes, as well as the transformation of the nitro group into other functionalities An exploration of the formation of C-C single bonds, C=C double bonds, and the breaking of C3C bonds from cyclic alpha-nitro ketones Discussions of acyclic alpha-nitro ketones, nitroalkanes as precursors of cyclopropanes, and the synthesis of spiro ketals An examination of the preparation and synthetic applications of 1,3-Dinitroalkanes Perfect for organic chemists, natural products chemists, and catalytic chemists, Nitroalkanes: Synthesis, Reactivity, and Applications will also earn a place in the libraries of medicinal chemists seeking a one-stop resource for the most recent developments in the preparation of nitroalkanes, their functionalization, and their applications.

Methods and Applications of Cycloaddition Reactions in Organic Syntheses

2013-12-17 Science
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Release : 2013-12-17
Genre : Science
Kind : eBook
Book Rating : 200/5 ( reviews)

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Book Synopsis Methods and Applications of Cycloaddition Reactions in Organic Syntheses by : Nagatoshi Nishiwaki

Download or read book Methods and Applications of Cycloaddition Reactions in Organic Syntheses written by Nagatoshi Nishiwaki. This book was released on 2013-12-17. Available in PDF, EPUB and Kindle. Book excerpt: Advanced tools for developing new functional materials and applications in chemical research, pharmaceuticals, and materials science Cycloadditions are among the most useful tools for organic chemists, enabling them to build carbocyclic and heterocyclic structures. These structures can then be used to develop a broad range of functional materials, including pharmaceuticals, agrochemicals, dyes, and optics. With contributions from an international team of leading experts and pioneers in cycloaddition chemistry, this book brings together and reviews recent advances, trends, and emerging research in the field. Methods and Applications of Cycloaddition Reactions in Organic Syntheses focuses on two component cycloadditions, with chapters covering such topics as: N1 unit transfer reaction to C–C double bonds [3+2] Cycloaddition of α, β-unsaturated metal-carbene complexes Formal [3+3] cycloaddition approach to natural product synthesis Development of new methods for the construction of heterocycles based on cycloaddition reaction of 1,3-dipoles Cycloreversion approach for preparation of large π-conjugated compounds Transition metal-catalyzed or mediated [5+1] cycloadditions Readers will learn methods for seamlessly executing important reactions such as Diels-Alder and stereoselective dipolar reactions in order to fabricate heterocyclic compounds, natural products, and functional molecules. The book not only features cutting-edge topics, but also important background information, such as the contributors’ process for developing new methodologies, to help novices become fully adept in the field. References at the end of each chapter lead to original research papers and reviews for facilitating further investigation of individual topics. Covering the state of the science and technology, Methods and Applications of Cycloaddition Reactions in Organic Syntheses enables synthetic organic chemists to advance their research and develop new functional materials and applications in chemical research, pharmaceuticals, and materials science.

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