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Lithium Metal Anodes and Rechargeable Lithium Metal Batteries

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Release : 2016-10-06
Genre : Technology & Engineering
Kind : eBook
Book Rating : 543/5 ( reviews)

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Book Synopsis Lithium Metal Anodes and Rechargeable Lithium Metal Batteries by : Ji-Guang Zhang

Download or read book Lithium Metal Anodes and Rechargeable Lithium Metal Batteries written by Ji-Guang Zhang. This book was released on 2016-10-06. Available in PDF, EPUB and Kindle. Book excerpt: This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential (−3.040 V vs. standard hydrogenelectrodes). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Liion batteries, safe and efficient operation of Li metal anodes has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes. In this work, various factors that affect the morphology and Coulombic efficiency of Li anodes are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anodes at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the applicationof Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.

Rechargeable Lithium Metal Batteries

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Release : 2024-10-07
Genre : Science
Kind : eBook
Book Rating : 693/5 ( reviews)

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Book Synopsis Rechargeable Lithium Metal Batteries by : Christian Julien

Download or read book Rechargeable Lithium Metal Batteries written by Christian Julien. This book was released on 2024-10-07. Available in PDF, EPUB and Kindle. Book excerpt: This monograph overviews cutting-edge advances in lithium metal batteries, showcasing a significant breakthrough in solving the longstanding issue of lithium dendrites. The key revelation is that this breakthrough paves the way for the development of lithium metal batteries, incorporating lithium metal anodes. The authors illustrate how overcoming the dendrite challenge leads to batteries with higher energy densities, enhanced safety, and further present a special focus on the development of all-solid-state batteries. This book not only highlights the scientific progress in solid-state batteries but also positions them as the next generation of rechargeable batteries. With a focus on bridging the gap from laboratory research to industrial development, the authors explain the profound implications of these advancements. Targeting a diverse audience, including PhD students aspiring to focus on future energy storage research and engineers involved in the transition from laboratory-scale prototypes to large-scale industrial development, this book serves as a comprehensive guide to the forefront of lithium battery technology.

Metal-Air Batteries

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Author :
Release : 2019-02-11
Genre : Technology & Engineering
Kind : eBook
Book Rating : 796/5 ( reviews)

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Book Synopsis Metal-Air Batteries by : Xin-bo Zhang

Download or read book Metal-Air Batteries written by Xin-bo Zhang. This book was released on 2019-02-11. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive overview of the research developments in the burgeoning field of metal-air batteries An innovation in battery science and technology is necessary to build better power sources for our modern lifestyle needs. One of the main fields being explored for the possible breakthrough is the development of metal-air batteries. Metal-Air Batteries: Fundamentals and Applications offers a systematic summary of the fundamentals of the technology and explores the most recent advances in the applications of metal-air batteries. Comprehensive in scope, the text explains the basics in electrochemical batteries and introduces various species of metal-air batteries. The author-a noted expert in the field-explores the development of metal-air batteries in the order of Li-air battery, sodium-air battery, zinc-air battery and Mg-O2 battery, with the focus on the Li-air battery. The text also addresses topics such as metallic anode, discharge products, parasitic reactions, electrocatalysts, mediator, and X-ray diffraction study in Li-air battery. Metal-Air Batteries provides a summary of future perspectives in the field of the metal-air batteries. This important resource: -Covers various species of metal-air batteries and their components as well as system designation -Contains groundbreaking content that reviews recent advances in the field of metal-air batteries -Focuses on the battery systems which have the greatest potential for renewable energy storage Written for electrochemists, physical chemists, materials scientists, professionals in the electrotechnical industry, engineers in power technology, Metal-Air Batteries offers a review of the fundamentals and the most recent developments in the area of metal-air batteries.

Theoretical Study on Graphite and Lithium Metal as Anode Materials for Next-Generation Rechargeable Batteries

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Release : 2022-07-08
Genre : Science
Kind : eBook
Book Rating : 144/5 ( reviews)

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Book Synopsis Theoretical Study on Graphite and Lithium Metal as Anode Materials for Next-Generation Rechargeable Batteries by : Gabin Yoon

Download or read book Theoretical Study on Graphite and Lithium Metal as Anode Materials for Next-Generation Rechargeable Batteries written by Gabin Yoon. This book was released on 2022-07-08. Available in PDF, EPUB and Kindle. Book excerpt: This thesis describes in-depth theoretical efforts to understand the reaction mechanism of graphite and lithium metal as anodes for next-generation rechargeable batteries. The first part deals with Na intercalation chemistry in graphite, whose understanding is crucial for utilizing graphite as an anode for Na-ion batteries. The author demonstrates that Na ion intercalation in graphite is thermodynamically unstable because of the unfavorable Na-graphene interaction. To address this issue, the inclusion of screening moieties, such as solvents, is suggested and proven to enable reversible Na-solvent cointercalation in graphite. Furthermore, the author provides the correlation between the intercalation behavior and the properties of solvents, suggesting a general strategy to tailor the electrochemical intercalation chemistry. The second part addresses the Li dendrite growth issue, which is preventing practical application of Li metal anodes. A continuum mechanics study considering various experimental conditions reveals the origins of irregular growth of Li metal. The findings provide crucial clues for developing effective counter strategies to control the Li metal growth, which will advance the application of high-energy-density Li metal anodes.

Lithium Metal Anodes and Rechargeable Lithium Metal Batteries

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Release : 2016-10-14
Genre : Technology & Engineering
Kind : eBook
Book Rating : 538/5 ( reviews)

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Book Synopsis Lithium Metal Anodes and Rechargeable Lithium Metal Batteries by : Ji-Guang Zhang

Download or read book Lithium Metal Anodes and Rechargeable Lithium Metal Batteries written by Ji-Guang Zhang. This book was released on 2016-10-14. Available in PDF, EPUB and Kindle. Book excerpt: This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential (−3.040 V vs. standard hydrogenelectrodes). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Liion batteries, safe and efficient operation of Li metal anodes has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes. In this work, various factors that affect the morphology and Coulombic efficiency of Li anodes are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anodes at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the applicationof Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.

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