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Author : Kang Xu
Release : 2023-04-12
Genre : Science
Kind : eBook
Book Rating : 100/5 ( reviews)
Book Synopsis Electrolytes, Interfaces and Interphases by : Kang Xu
Download or read book Electrolytes, Interfaces and Interphases written by Kang Xu. This book was released on 2023-04-12. Available in PDF, EPUB and Kindle. Book excerpt: The authoritative textbook for those who want to enter the field of electrochemical energy storage research.
Author : Perla B. Balbuena
Release : 2004
Genre : Science
Kind : eBook
Book Rating : 624/5 ( reviews)
Book Synopsis Lithium-ion Batteries by : Perla B. Balbuena
Download or read book Lithium-ion Batteries written by Perla B. Balbuena. This book was released on 2004. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The SEI film is due to electromechanical reduction of species present in the electrolyte. It is widely recognized that the presence of the film plays an essential role in the battery performance, and its very nature can determine an extended (or shorter) life for the battery. In spite of the numerous related research efforts, details on the stability of the SEI composition and its influence on the battery capacity are still controversial. This book carefully analyzes and discusses the most recent findings and advances on this topic.
Author : S. Durand-Vidal
Release : 2006-04-11
Genre : Science
Kind : eBook
Book Rating : 405/5 ( reviews)
Book Synopsis Electrolytes at Interfaces by : S. Durand-Vidal
Download or read book Electrolytes at Interfaces written by S. Durand-Vidal. This book was released on 2006-04-11. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this book is to provide the reader with a modern presentation of ionic solutions at interfaces, for physical chemists, chemists and theoretically oriented experimentalists in this field. The discussion is mainly on the structural and thermodynamic properties, in relation to presently available statistical mechanical models. Some dynamic properties are also presented, at a more phenomenological level. The initial chapters are devoted to the presentation of some basic concepts for bulk properties: hydrodynamic interactions, electrostatics, van der Waals forces and thermodynamics of ionic solutions in the framework of a particular model: the mean spherical approximation (MSA). Specific features of interfaces are then discussed: experimental techniques such as in-situ X-ray diffraction, STM and AFM microscopy are described. Ions at liquid/air, liquid/metal and liquid/liquid interfaces are considered from the experimental and theoretical viewpoint. Lastly some dynamic (transport) properties are included, namely the self-diffusion and conductance of small colloids (polyelectrolytes and micelles) and the kinetics of solute transfer at free liquid/liquid interfaces.
Author : T. Richard Jow
Release : 2014-05-06
Genre : Technology & Engineering
Kind : eBook
Book Rating : 020/5 ( reviews)
Book Synopsis Electrolytes for Lithium and Lithium-Ion Batteries by : T. Richard Jow
Download or read book Electrolytes for Lithium and Lithium-Ion Batteries written by T. Richard Jow. This book was released on 2014-05-06. Available in PDF, EPUB and Kindle. Book excerpt: Electrolytes for Lithium and Lithium-ion Batteries provides a comprehensive overview of the scientific understanding and technological development of electrolyte materials in the last several years. This book covers key electrolytes such as LiPF6 salt in mixed-carbonate solvents with additives for the state-of-the-art Li-ion batteries as well as new electrolyte materials developed recently that lay the foundation for future advances. This book also reviews the characterization of electrolyte materials for their transport properties, structures, phase relationships, stabilities, and impurities. The book discusses in-depth the electrode-electrolyte interactions and interphasial chemistries that are key for the successful use of the electrolyte in practical devices. The Quantum Mechanical and Molecular Dynamical calculations that has proved to be so powerful in understanding and predicating behavior and properties of materials is also reviewed in this book. Electrolytes for Lithium and Lithium-ion Batteries is ideal for electrochemists, engineers, researchers interested in energy science and technology, material scientists, and physicists working on energy.
Author : Snehashis Choudhury
Release : 2019-09-25
Genre : Technology & Engineering
Kind : eBook
Book Rating : 435/5 ( reviews)
Book Synopsis Rational Design of Nanostructured Polymer Electrolytes and Solid–Liquid Interphases for Lithium Batteries by : Snehashis Choudhury
Download or read book Rational Design of Nanostructured Polymer Electrolytes and Solid–Liquid Interphases for Lithium Batteries written by Snehashis Choudhury. This book was released on 2019-09-25. Available in PDF, EPUB and Kindle. Book excerpt: This thesis makes significant advances in the design of electrolytes and interfaces in electrochemical cells that utilize reactive metals as anodes. Such cells are of contemporary interest because they offer substantially higher charge storage capacity than state-of-the-art lithium-ion battery technology. Batteries based on metallic anodes are currently considered impractical and unsafe because recharge of the anode causes physical and chemical instabilities that produce dendritic deposition of the metal leading to catastrophic failure via thermal runaway. This thesis utilizes a combination of chemical synthesis, physical & electrochemical analysis, and materials theory to investigate structure, ion transport properties, and electrochemical behaviors of hybrid electrolytes and interfacial phases designed to prevent such instabilities. In particular, it demonstrates that relatively low-modulus electrolytes composed of cross-linked networks of polymer-grafted nanoparticles stabilize electrodeposition of reactive metals by multiple processes, including screening electrode electrolyte interactions at electrochemical interfaces and by regulating ion transport in tortuous nanopores. This discovery is significant because it overturns a longstanding perception in the field of nanoparticle-polymer hybrid electrolytes that only solid electrolytes with mechanical modulus higher than that of the metal electrode are able to stabilize electrodeposition of reactive metals.
