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Direct Synthesis of Metal Complexes

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Release : 2018-04-19
Genre : Science
Kind : eBook
Book Rating : 627/5 ( reviews)

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Book Synopsis Direct Synthesis of Metal Complexes by : B.I. Kharisov

Download or read book Direct Synthesis of Metal Complexes written by B.I. Kharisov. This book was released on 2018-04-19. Available in PDF, EPUB and Kindle. Book excerpt: Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter

Electrochemistry of Metal Complexes

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Release : 2015-06-29
Genre : Science
Kind : eBook
Book Rating : 772/5 ( reviews)

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Book Synopsis Electrochemistry of Metal Complexes by : Arvydas Survila

Download or read book Electrochemistry of Metal Complexes written by Arvydas Survila. This book was released on 2015-06-29. Available in PDF, EPUB and Kindle. Book excerpt: A systematic analysis of electrochemical processes involving metal complexes. Starting with general considerations on equilibria in solutions and at interfaces as well as on mass transport, the text acquaints readers with the theory and common experimental practice for studying electrochemical reactions of metals complexes. The core part of the book deals with all important aspects of electroplating, including a systematic discussion of co-deposition of metals and formation of alloys. It also discusses such related subjects as oxide layer formation and hydrogen evolution as a side reaction.

Electrochemistry of N4 Macrocyclic Metal Complexes

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Release : 2016-04-20
Genre : Science
Kind : eBook
Book Rating : 727/5 ( reviews)

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Book Synopsis Electrochemistry of N4 Macrocyclic Metal Complexes by : Jose H. Zagal

Download or read book Electrochemistry of N4 Macrocyclic Metal Complexes written by Jose H. Zagal. This book was released on 2016-04-20. Available in PDF, EPUB and Kindle. Book excerpt: This new edition describes the state of the art regarding molecular catalysts such as MN4 metal complexes, like porphyrins and phthalocyanines. This volume focuses on the particular case of the electrocatalysis of the reduction of O2 for practical applications in fuel cells and air batteries. Indeed, active and stable materials have been developed in the last 5 years where MN4 catalytic systems can be obtained by the pyrolysis of starting materials that do not necessarily involve MN4 complexes. These latter systems constitute a new class of stable and highly active non-precious metal catalysts for ORR that can replace expensive Platinum containing electrodes. The book also offers future projections and points out new fields of research and development of these non-precious metal catalysts.

Electrochemistry of Metal Chalcogenides

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Release : 2010-04-23
Genre : Science
Kind : eBook
Book Rating : 677/5 ( reviews)

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Book Synopsis Electrochemistry of Metal Chalcogenides by : Mirtat Bouroushian

Download or read book Electrochemistry of Metal Chalcogenides written by Mirtat Bouroushian. This book was released on 2010-04-23. Available in PDF, EPUB and Kindle. Book excerpt: The author provides a unified account of the electrochemical material science of metal chalcogenide (MCh) compounds and alloys with regard to their synthesis, processing and applications. Starting with the chemical fundamentals of the chalcogens and their major compounds, the initial part of the book includes a systematic description of the MCh solids on the basis of the Periodic Table in terms of their structures and key properties. This is followed by a general discussion on the electrochemistry of chalcogen species, and the principles underlying the electrochemical formation of inorganic compounds/alloys. The core of the book offers an insight into available experimental results and inferences regarding the electrochemical preparation and microstructural control of conventional and novel MCh structures. It also aims to survey their photoelectrochemistry, both from a material-oriented point of view and as connected to specific processes such as photocatalysis and solar energy conversion. Finally, the book illustrates the relevance of MCh materials to various applications of electrochemical interest such as (electro)catalysis in fuel cells, energy storage with intercalation electrodes, and ion sensing.

N4-Macrocyclic Metal Complexes

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Release : 2007-07-16
Genre : Science
Kind : eBook
Book Rating : 303/5 ( reviews)

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Book Synopsis N4-Macrocyclic Metal Complexes by : J.H. Zagal

Download or read book N4-Macrocyclic Metal Complexes written by J.H. Zagal. This book was released on 2007-07-16. Available in PDF, EPUB and Kindle. Book excerpt: In response to significant developments in sensor science and technology, this book offers insight into the various extended applications and developments of N4 macrocycle complexes in biomimetic electrocatalysis. Chapters are devoted to the chemistry, electronic and electrochemical properties of porphyrin- based polymetallated supramolecular redox catalysts and their applications in analytical and photoelectrochemical molecular devices; the use of porphyrins, phthalocyanines and related complexes as electrocatalysts for the detection of a wide variety of environmentally polluting and biologically relevant molecules; and the use of electropolymerized metalloporphyrin and metallophthalocyanine films as powerful materials for analytical tools, especially for sensing biologically relevant species.

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