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Electrochemical Reactions and Mechanisms in Organic Chemistry

2000-12-01 Science
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Release : 2000-12-01
Genre : Science
Kind : eBook
Book Rating : 729/5 ( reviews)

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Book Synopsis Electrochemical Reactions and Mechanisms in Organic Chemistry by : J. Grimshaw

Download or read book Electrochemical Reactions and Mechanisms in Organic Chemistry written by J. Grimshaw. This book was released on 2000-12-01. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemical reactions make significant contributions to organic synthesis either in the laboratory or on an industrial scale. These methods have the potential for developing more "green" chemical synthesis. Over recent years, modern investigations have clarified the mechanisms of important organic electrochemical reactions. Progress has also been made in controlling the reactivity of intermediates through either radical or ionic pathways. Now is the time to gather all the electrochemical work into a textbook. As an essential addition to the armory of synthetic organic chemists, electrochemical reactions give results not easily achieved by many other chemical routes. This book presents a logical development of reactions and mechanisms in organic electrochemistry at a level suited to research scientists and final year graduate students. It forms an excellent starting point from which synthetic organic chemists, in both academia and industry, can appreciate uses for electrochemical methods in their own work. The book is also a reference guide to the literature.

The Investigation of Organic Reactions and Their Mechanisms

2008-04-15 Science
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Release : 2008-04-15
Genre : Science
Kind : eBook
Book Rating : 169/5 ( reviews)

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Book Synopsis The Investigation of Organic Reactions and Their Mechanisms by : Howard Maskill

Download or read book The Investigation of Organic Reactions and Their Mechanisms written by Howard Maskill. This book was released on 2008-04-15. Available in PDF, EPUB and Kindle. Book excerpt: A range of alternative mechanisms can usually be postulated for most organic chemical reactions, and identification of the most likely requires detailed investigation. Investigation of Organic Reactions and their Mechanisms will serve as a guide for the trained chemist who needs to characterise an organic chemical reaction and investigate its mechanism, but who is not an expert in physical organic chemistry. Such an investigation will lead to an understanding of which bonds are broken, which are made, and the order in which these processes happen. This information and knowledge of the associated kinetic and thermodynamic parameters are central to the development of safe, efficient, and profitable industrial chemical processes, and to extending the synthetic utility of new chemical reactions in chemical and pharmaceutical manufacturing, and academic environments. Written as a coherent account of the principal methods currently used in mechanistic investigations, at a level accessible to academic researchers and graduate chemists in industry, the book is highly practical in approach. The contributing authors, an international group of expert practitioners of the techniques covered, illustrate their contributions by examples from their own research and from the relevant wider chemical literature. The book covers basic aspects such as product analysis, kinetics, catalysis, and investigation of reactive intermediates. It also includes material on significant recent developments, e.g. computational chemistry, calorimetry, and electrochemistry, in addition to topics of high current industrial relevance, e.g. reactions in multiphase systems, and synthetically useful reactions involving free radicals and catalysis by organometallic compounds.

Fundamentals and Applications of Organic Electrochemistry

2014-11-10 Science
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Release : 2014-11-10
Genre : Science
Kind : eBook
Book Rating : 173/5 ( reviews)

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Book Synopsis Fundamentals and Applications of Organic Electrochemistry by : Toshio Fuchigami

Download or read book Fundamentals and Applications of Organic Electrochemistry written by Toshio Fuchigami. This book was released on 2014-11-10. Available in PDF, EPUB and Kindle. Book excerpt: This textbook is an accessible overview of the broad field of organic electrochemistry, covering the fundamentals and applications of contemporary organic electrochemistry. The book begins with an introduction to the fundamental aspects of electrode electron transfer and methods for the electrochemical measurement of organic molecules. It then goes on to discuss organic electrosynthesis of molecules and macromolecules, including detailed experimental information for the electrochemical synthesis of organic compounds and conducting polymers. Later chapters highlight new methodology for organic electrochemical synthesis, for example electrolysis in ionic liquids, the application to organic electronic devices such as solar cells and LEDs, and examples of commercialized organic electrode processes. Appendices present useful supplementary information including experimental examples of organic electrosynthesis, and tables of physical data (redox potentials of various organic solvents and organic compounds and physical properties of various organic solvents).

The Mechanisms of the Electrochemical Reactions of Simple Organic Compounds in Aqueous Solutions

1970
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Release : 1970
Genre :
Kind : eBook
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Book Synopsis The Mechanisms of the Electrochemical Reactions of Simple Organic Compounds in Aqueous Solutions by : S. B. Brummer

Download or read book The Mechanisms of the Electrochemical Reactions of Simple Organic Compounds in Aqueous Solutions written by S. B. Brummer. This book was released on 1970. Available in PDF, EPUB and Kindle. Book excerpt: Research to further the understanding of the anode of a hydrocarbon fuel cell is reported. Studies of simple organic reactions, e.g., the reduction of CO2, the oxidation of HCOOH, and the effects of adsorbed layers on their reactions in acid solutions are reported. Methods of determining the properties of adsorbate layers are experimentally and theoretically explored. Methods to allow determination of double layer charging effects and electrode oxidation corrections are developed. Studies of the Pt electrocatalytic surface show it to be markedly heterogeneous. Studies of the formation of 'reduced CO2', the main intermediate in hydrocarbon oxidation, have been carried out. The mechanism of HCOOH oxidation has been explored. It has been shown that the product of a side reaction blocks the electrode and inhibits the desired reaction. The electroactive species is apparently HCOO( - ). The effects of adsorbed inorganic layers on HCOOH oxidation have been studied with a view to developing a non-noble metal catalyst stabilized by adsorption. Experiments with Cu, Ag, Pb, Hg, S, and Cl( - ) are reported. The most reactive layers are Pb, Hg, and S. (Author).

Electroorganic Chemistry as a New Tool in Organic Synthesis

2012-12-06 Science
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Release : 2012-12-06
Genre : Science
Kind : eBook
Book Rating : 934/5 ( reviews)

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Book Synopsis Electroorganic Chemistry as a New Tool in Organic Synthesis by : Tatsuya Shono

Download or read book Electroorganic Chemistry as a New Tool in Organic Synthesis written by Tatsuya Shono. This book was released on 2012-12-06. Available in PDF, EPUB and Kindle. Book excerpt: Although the first electroorganic reaction used in organic synthesis is probably the famous Kolbe electrolysis published in 1849, no other remarkable reactions have been found until the reductive dimerization of acrylonitrile to adipo nitrile was developed by Dr. M. M. Baizer of Monsanto Co. in 1964. Since then, the electro organic chemistry has been studied extensively with the expectation that it is a new useful tool for finding novel reactions in organic synthesis. The purpose of this book is not to give a comprehensive survey of studies on electrochemical reactions of organic compounds but to show that the electro organic chemistry is indeed useful in organic synthesis. Thus, this book has been written under the following policies. (1) Since this monograph is mainly concerned with organic synthesis, only few studies carried out from the view point of electrochemical, theoretical, or analytical chemistry are mentioned. (2) Since electroorganic chemistry covers a great variety of reactions, the types of reactions described in this book are selected mainly with regard to their application in organic synthesis. Simple transformations of functional groups are only described in particular cases, and also some well established processes such as the Kolbe electrolysis, pinacolic coupling, and hydrodimerization are only briefly mentioned. (3) Since many reports have already been published for each type of these reactions, only a limited number of the relevant papers are cited in this book.

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