An Investigation of the Effect of Pore Scale Flow on Average Geochemical Reaction Rates Using Direct Numerical Simulation

2012

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Release : 2012
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Book Synopsis An Investigation of the Effect of Pore Scale Flow on Average Geochemical Reaction Rates Using Direct Numerical Simulation by :

Download or read book An Investigation of the Effect of Pore Scale Flow on Average Geochemical Reaction Rates Using Direct Numerical Simulation written by . This book was released on 2012. Available in PDF, EPUB and Kindle. Book excerpt: The scale-dependence of geochemical reaction rates hinders their use in continuum scale models intended for the interpretation and prediction of chemical fate and transport in subsurface environments such as those considered for geologic sequestration of CO2. Processes that take place at the pore scale, especially those involving mass transport limitations to reactive surfaces, may contribute to the discrepancy commonly observed between laboratory-determined and continuum-scale or field rates. In this study we investigate the dependence of mineral dissolution rates on the pore structure of the porous media by means of pore scale modeling of flow and multicomponent reactive transport. The pore scale model is composed of high-performance simulation tools and algorithms for incompressible flow and conservative transport combined with a general-purpose multicomponent geochemical reaction code. The model performs direct numerical simulation of reactive transport based on an operator-splitting approach to coupling transport and reactions. The approach is validated with a Poiseuille flow single-pore experiment and verified with an equivalent 1-D continuum-scale model of a capillary tube packed with calcite spheres. Using the case of calcite dissolution as an example, the high-resolution model is used to demonstrate that nonuniformity in the flow field at the pore scale has the effect of decreasing the overall reactivity of the system, even when systems with identical reactive surface area are considered. In conclusion, the effect becomes more pronounced as the heterogeneity of the reactive grain packing increases, particularly where the flow slows sufficiently such that the solution approaches equilibrium locally and the average rate becomes transport-limited.

Pore Scale Geochemical Processes

2015-09-25 Science

Author : Carl Steefel
Release : 2015-09-25
Genre : Science
Kind : eBook
Book Rating : 077/5 ( reviews)

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Book Synopsis Pore Scale Geochemical Processes by : Carl Steefel

Download or read book Pore Scale Geochemical Processes written by Carl Steefel. This book was released on 2015-09-25. Available in PDF, EPUB and Kindle. Book excerpt: This RiMG (Reviews in Mineralogy & Geochemistry) volume includes contributions that review experimental, characterization, and modeling advances in our understanding of pore-scale geochemical processes. The volume had its origins in a special theme session at the 2015 Goldschmidt Conference in Prague. From a diversity of pore-scale topics that ranged from multi-scale characterization to modeling, this work summarizes the state-of-the-science in this subject. Topics include: modification of thermodynamics and kinetics in small pores. chemo-mechanical processes and how they affect porosity evolution in geological media. small angle neutron scattering (SANS) techniques. how isotopic gradients across fluid–mineral boundaries can develop and how these provide insight into pore-scale processes. Information on an important class of models referred to as "pore network" and much more. The material in this book is accessible for graduate students, researchers, and professionals in the earth, material, environmental, hydrological, and biological sciences. The pore scale is readily recognizable to geochemists, and yet in the past it has not received a great deal of attention as a distinct scale or environment that is associated with its own set of questions and challenges. Is the pore scale merely an environment in which smaller scale (molecular) processes aggregate, or are there emergent phenomena unique to this scale? Is it simply a finer-grained version of the "continuum" scale that is addressed in larger-scale models and interpretations? The scale is important because it accounts for the pore architecture within which such diverse processes as multi-mineral reaction networks, microbial community interaction, and transport play out, giving rise to new geochemical behavior that might not be understood or predicted by considering smaller or larger scales alone.

Geochemistry of Geologic CO2 Sequestration

2018-12-17 Science

Author : Donald J. DePaolo
Release : 2018-12-17
Genre : Science
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Book Rating : 075/5 ( reviews)

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Book Synopsis Geochemistry of Geologic CO2 Sequestration by : Donald J. DePaolo

Download or read book Geochemistry of Geologic CO2 Sequestration written by Donald J. DePaolo. This book was released on 2018-12-17. Available in PDF, EPUB and Kindle. Book excerpt: Volume 77 of Reviews in Mineralogy and Geochemistry focuses on important aspects of the geochemistry of geological CO2 sequestration. It is in large part an outgrowth of research conducted by members of the U.S. Department of Energy funded Energy Frontier Research Center (EFRC) known as the Center for Nanoscale Control of Geologic CO2 (NCGC). Eight out of the 15 chapters have been led by team members from the NCGC representing six of the eight partner institutions making up this center - Lawrence Berkeley National Laboratory (lead institution, D. DePaolo - PI), Oak Ridge National Laboratory, The Ohio State University, the University of California Davis, Pacific Northwest National Laboratory, and Washington University, St. Louis.

Percolation Theory for Flow in Porous Media

2014-02-04 Science

Author : Allen Hunt
Release : 2014-02-04
Genre : Science
Kind : eBook
Book Rating : 714/5 ( reviews)

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Book Synopsis Percolation Theory for Flow in Porous Media by : Allen Hunt

Download or read book Percolation Theory for Flow in Porous Media written by Allen Hunt. This book was released on 2014-02-04. Available in PDF, EPUB and Kindle. Book excerpt: This monograph presents, for the first time, a unified and comprehensive introduction to some of the basic transport properties of porous media, such as electrical and hydraulic conductivity, air permeability and diffusion. The approach is based on critical path analysis and the scaling of transport properties, which are individually described as functions of saturation. At the same time, the book supplies a tutorial on percolation theory for hydrologists, providing them with the tools for solving actual problems. In turn, a separate chapter serves to introduce physicists to some of the language and complications of groundwater hydrology necessary for successful modeling. The end-of-chapter problems often indicate open questions, which young researchers entering the field can readily start working on. This significantly revised and expanded third edition includes in particular two new chapters: one on advanced fractal-based models, and one devoted to the discussion of various open issues such as the role of diffusion vs. advection, preferential flow vs. critical path, universal vs. non-universal exponents for conduction, and last but not least, the overall influence of the experimental apparatus in data collection and theory validation. "The book is suitable for advanced graduate courses, with selected problems and questions appearing at the end of each chapter. [...] I think the book is an important work that will guide soil scientists, hydrologists, and physicists to gain a better qualitative and quantitative understanding of multitransport properties of soils." (Marcel G. Schaap, Soil Science Society of America Journal, May-June, 2006)

Heat and Mass Transfer

2018-09-19 Technology & Engineering

Author :
Release : 2018-09-19
Genre : Technology & Engineering
Kind : eBook
Book Rating : 726/5 ( reviews)

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Book Synopsis Heat and Mass Transfer by :

Download or read book Heat and Mass Transfer written by . This book was released on 2018-09-19. Available in PDF, EPUB and Kindle. Book excerpt: Heat and mass transfer are ubiquitous transport phenomena in many fields, from the natural environment and living organisms to the engineering process. This book focuses on the latest advances in applying fundamental heat and mass transfer theory and novel technologies for addressing a wide range of industrial problems of interest. This book will present readers with a recent analytical study, CFD modelling, and experimental investigations of heat and mass transfer topics associated with a variety of engineering disciplines including multiphase flow, nanofluids, porous media, battery thermal management, and engineering processes such as extractive distillation and arc welding. The book aims to provide new insights to understand the heat and mass transfer phenomena, serving as a platform for exchanging inspiring ideas and boosting further development of these disciplines.

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