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Author : A.E. Shilov
Release : 1984-06-30
Genre : Science
Kind : eBook
Book Rating : 286/5 ( reviews)
Book Synopsis Activation of Saturated Hydrocarbons by Transition Metal Complexes by : A.E. Shilov
Download or read book Activation of Saturated Hydrocarbons by Transition Metal Complexes written by A.E. Shilov. This book was released on 1984-06-30. Available in PDF, EPUB and Kindle. Book excerpt:
Author : A.E. Shilov
Release : 2006-04-11
Genre : Science
Kind : eBook
Book Rating : 456/5 ( reviews)
Book Synopsis Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes by : A.E. Shilov
Download or read book Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes written by A.E. Shilov. This book was released on 2006-04-11. Available in PDF, EPUB and Kindle. Book excerpt: hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the “noble gases of organic chemistry” and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint.
Author : Aleksandr Evgenʹevich Shilov
Release : 2000
Genre : Activation (Chemistry)
Kind : eBook
Book Rating : /5 ( reviews)
Book Synopsis Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes by : Aleksandr Evgenʹevich Shilov
Download or read book Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes written by Aleksandr Evgenʹevich Shilov. This book was released on 2000. Available in PDF, EPUB and Kindle. Book excerpt: Hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C-H, as well as C-C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc.), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the "noble gases of organic chemistry" and, if so, the first representative of their family - methane - may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning - the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300-500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process - but not from a chemist viewpoint.
Author : László I. Simándi
Release : 2012-12-06
Genre : Science
Kind : eBook
Book Rating : 502/5 ( reviews)
Book Synopsis Catalytic Activation of Dioxygen by Metal Complexes by : László I. Simándi
Download or read book Catalytic Activation of Dioxygen by Metal Complexes written by László I. Simándi. This book was released on 2012-12-06. Available in PDF, EPUB and Kindle. Book excerpt: The activation of dioxygen by metal ions has both synthetic potential and biological relevance. Dioxygen is the cleanest oxidant for use in emission-free technologies to minimize pollution of the environment. The book gives a survey of those catalyst systems based on metal complexes which have been discovered and studied in the last decade. They activate molecular oxygen and effect the oxidation of various organic compounds under mild conditions. Much of the recent progress is due to a search for biomimetic catalysts that would duplicate the action of metalloenzymes. Mechanistic aspects are emphasized throughout the book. An introductonary chapter reviews the chemistry of transition metal dioxygen complexes, which are usually the active intermediates in the catalytic reactions discussed. Separate chapters are devoted to oxidation of saturated, unsaturated and aromatic hydrocarbons, phenols, catechols, oxo-compounds, phosphorus, sulfur and nitrogen compounds.
Author : T. D. McLean
Release : 1984
Genre : Hydrocarbons
Kind : eBook
Book Rating : /5 ( reviews)
Book Synopsis New Routes for the Activation of Hydrocarbons by Transition Metal Complexes by : T. D. McLean
Download or read book New Routes for the Activation of Hydrocarbons by Transition Metal Complexes written by T. D. McLean. This book was released on 1984. Available in PDF, EPUB and Kindle. Book excerpt:
