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Structure-property Relationships in Dynamic Polymer Networks

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Release : 2023
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Book Synopsis Structure-property Relationships in Dynamic Polymer Networks by : Christopher Brittain Cooper

Download or read book Structure-property Relationships in Dynamic Polymer Networks written by Christopher Brittain Cooper. This book was released on 2023. Available in PDF, EPUB and Kindle. Book excerpt: Many emerging applications including wearable electronics and e-skins, soft robotics and actuators, and biomaterials, require material platforms with precisely controlled mechanical, electrical, thermal, and optical properties. The practical realization of devices for these applications is often restricted not by the lack of novel designs, but rather by the sparsity of materials with the required properties. Dynamic polymers, which employ both permanent and reversible linkages, offer a promising platform for the design of new materials due to their highly tunable and responsive chemical structures. This dissertation explores structure-property relationships in different dynamic polymer networks with well-defined polymer design and is structured as follows. Chapter 1 introduces the concept of dynamic polymers, provides comparisons to supramolecular polymers and segmented block copolymers, and concludes with emerging applications for these systems. Chapter 2 examines the molecular design rules for spontaneous self-assembly of periodic dynamic polymers into supramolecular nanofibers. Chapter 3 discusses the phenomenon of strain-induced supramolecular structures exhibited by entangled periodic dynamic polymers. Chapter 4 highlights how the clustered nanomorphology exhibited by periodic dynamic polymers can be used to design recyclable underwater adhesives. Chapter 5 explains how immiscible dynamic polymers can be used to achieve autonomous alignment of multilayered soft electronics. Chapter 6 concludes with key observations and on the future outlook of next-generation materials.

Structure—Property Relationships in Polymers

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Release : 2012-12-06
Genre : Science
Kind : eBook
Book Rating : 483/5 ( reviews)

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Book Synopsis Structure—Property Relationships in Polymers by : Charles E. Carraher Jr.

Download or read book Structure—Property Relationships in Polymers written by Charles E. Carraher Jr.. This book was released on 2012-12-06. Available in PDF, EPUB and Kindle. Book excerpt: The first concern of scientists who are interested in synthetic polymers has always been, and still is: How are they synthesized? But right after this comes the question: What have I made, and for what is it good? This leads to the important topic of the structure-property relations to which this book is devoted. Polymers are very large and very complicated systems; their character ization has to begin with the chemical composition, configuration, and con formation of the individual molecule. The first chapter is devoted to this broad objective. The immediate physical consequences, discussed in the second chapter, form the basis for the physical nature of polymers: the supermolecular interactions and arrangements of the individual macromolecules. The third chapter deals with the important question: How are these chemical and physical structures experimentally determined? The existing methods for polymer characterization are enumerated and discussed in this chapter. The following chapters go into more detail. For most applications-textiles, films, molded or extruded objects of all kinds-the mechanical and the thermal behaviors of polymers are of pre ponderant importance, followed by optical and electric properties. Chapters 4 through 9 describe how such properties are rooted in and dependent on the chemical structure. More-detailed considerations are given to certain particularly important and critical properties such as the solubility and permeability of polymeric systems. Macromolecules are not always the final goal of the chemist-they may act as intermediates, reactants, or catalysts. This topic is presented in Chapters 10 and 11.

Structure-property Relationships in Thiol-based Polymer Networks

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Release : 2001
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Book Synopsis Structure-property Relationships in Thiol-based Polymer Networks by : Michael Taylor

Download or read book Structure-property Relationships in Thiol-based Polymer Networks written by Michael Taylor. This book was released on 2001. Available in PDF, EPUB and Kindle. Book excerpt:

Structure-property Relationships of Novel Polymer Networks

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Release : 1995
Genre : Copolymers
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Book Synopsis Structure-property Relationships of Novel Polymer Networks by : Dongkyu Park

Download or read book Structure-property Relationships of Novel Polymer Networks written by Dongkyu Park. This book was released on 1995. Available in PDF, EPUB and Kindle. Book excerpt:

Structures and Properties of Rubberlike Networks

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Release : 1997
Genre : Science
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Book Rating : 370/5 ( reviews)

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Book Synopsis Structures and Properties of Rubberlike Networks by : Burak Erman

Download or read book Structures and Properties of Rubberlike Networks written by Burak Erman. This book was released on 1997. Available in PDF, EPUB and Kindle. Book excerpt: Rubber elasticity is an important sub-field of polymer science. This book is in many ways a sequel to the authors' previous, more introductory book, Rubberlike Elasticity: A Molecular Primer (Wiley-Interscience, 1988), and will in some respects replace the now classic book by L.R.G. Treloar, The Physics of Rubber Elasticity (Oxford, 1975). The present book has much in common with its predecessor, in particular its strong emphasis on molecular concepts and theories. Similarly, only equilibrium properties are covered in any detail. Though this book treats much of the same subject matter, it is a more comprehensive, more up-to-date, and somewhat more sophisticated treatment.

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